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willysmjeeps.com :: View topic - Necessary zinc & phosphate levels in engine oil
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Necessary zinc & phosphate levels in engine oil

 
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wesk
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PostPosted: Thu Oct 18, 2012 12:17 pm    Post subject: Necessary zinc & phosphate levels in engine oil Reply with quote

Here's a good read:
http://blog.hemmings.com/index.php/2012/10/18/tech-101-zinc-in-oil-and-its-effects-on-older-engines/?refer=news
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Wes K
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Xamon
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PostPosted: Thu Oct 18, 2012 2:20 pm    Post subject: Reply with quote

Facinating information and definatly something to consider when rebuilding one of these. I am curious doo they give zinc specs in the manuals? gonna have to do a read...
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TomM
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PostPosted: Thu Oct 18, 2012 3:26 pm    Post subject: Reply with quote

60 years ago nobody anticipated we would have the efforts against pollutions that exist today. Motor oil was motor oil and I doubt they even had the tools needed to measure what they look at today.
Manufacturers had notice since they started moving to roller motors in the 90's.

We can be glad we work on lower stressed engines rather than the big high winding V8's from the 60's.
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wesk
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PostPosted: Thu Oct 18, 2012 9:33 pm    Post subject: Reply with quote

Zinc content was the norm in the 50's thru the 70's. The reduction a little every few years is what has snuck up on us old car operators. Although our engines don't normally suufer the stress levels a 60's big Go Motor like the 428's, 396's, 406's, 426's and so on from that period we still endure the dry startups every time we let the old girl set for a week or more. This reults in shortening the life of the cam followers and the cam and hat fuel pump lobe!
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Wes K
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frankthecrank58
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PostPosted: Fri Oct 19, 2012 10:33 am    Post subject: Reply with quote

i was talking with a guy in a performance parts store about my '52 and he said the same about low zinc in modern oil. he told me of a product he uses, which is called " Joe Gibbs Racing Oil ". it's available here at Mopac. i haven't done any research yet because i'm not at the rebuild stage yet. doing the body work first since that will probably take longest
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RICKG
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PostPosted: Fri Oct 19, 2012 1:26 pm    Post subject: Reply with quote

frankthecrank58 wrote:
he told me of a product he uses, which is called " Joe Gibbs Racing Oil ".


My engine builder (a performance guy) provided this product with
my fresh motor as the break-in oil. It's spendy but for as few miles as some of us put on our trucks and the time between oil changes
it's not cost
prohibitive. He suggested that he would warranty my rebuild as long
as i used this (joe gibbs) or equal.
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wilfreeman
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PostPosted: Sat Oct 20, 2012 6:34 am    Post subject: Reply with quote

STP or Lucas - there are different schools of thought here, but they have been on the market for a long time for a reason - and they are still cheap insurance!
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timjuhl
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PostPosted: Sat Oct 20, 2012 5:37 pm    Post subject: oil Reply with quote

For better or worse I've been using Shell 15W-40 Rotella T Triple Protection oil which has approximately 1200 ppm of zinc and 1100 ppm phosphorus at the time of manufacture.

Tim
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MrWillys
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PostPosted: Fri Aug 16, 2013 2:03 am    Post subject: Reply with quote

So what would be the correct engine oil for my 43 Willys?
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wesk
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PostPosted: Fri Aug 16, 2013 7:53 am    Post subject: Reply with quote

Just print the article referred to above and carry to your local oil distributor and buy the oil that has the proper contents. Since you are outside the US it would be unwise for us to name a brand for you.

http://blog.hemmings.com/index.php/2012/10/18/tech-101-zinc-in-oil-and-its-effects-on-older-engines/?refer=news


Quote:
[Editor's Note: After the conversation following our introduction of the Hemmings Motor News Motor Oil last month, we turned to our tech guru, Jim O'Clair, for an explanation of the problems classic car owners have when choosing a modern motor oil.]

There has been a lot of confusion in the last few years about the lowering of zinc and phosphorus levels in modern oils and how these lower levels relate to classic and performance engines using standard flat tappet lifters – that is, just about every car built before the Eighties. The concern involves the use of the new lower zinc/phosphorus-content ILSAC (multi-viscosity) oils, readily available on shelves at auto parts stores everywhere, and how compatible they are with these older engines.

When anyone mentions zinc, they are actually referring to zinc dialkyldithiophosphate, a compound invented by Castrol for use in mineral-based oils or zinc di-thiophosphate (ZDTP), which is normally used in synthetic oils. Both have been used as an anti-wear ingredient in engine oil for many years. The zinc and phosphorus ingredients appear to be most effective when they are used together. ZDDP/ZDTP is one of many additives that are put into conventional motor oil to improve its lubrication qualities. Other ingredients such as boron and molybdenum are also added as lubricant enhancers.

What was discovered through oil testing by several engine component manufacturers is that many older engines experience a short period of time during engine start-up where critical lubrication is insufficient between metal-to-metal lubrication points when using modern oils with reduced amounts of ZDDP/ZDTP. These same enhancers unfortunately have their downside: The phosphorus in this compound creates carbon buildup in engine bores and valvetrains, and both compounds can also lead to the early demise of catalytic converters. For this reason, the industry has been phasing out zinc and phosphorus levels since 1994, when the American Petroleum Institute’s SH designation became the industry standard, and levels have been further reduced in each subsequent API rating for engine oils. Manufacturers have tried adding more boron to offset the effects of the reduced zinc and phosphorus levels; however, the dry start protection does not measure up to those using more ZDDP/ZDTP. This has opened up a whole new market for zinc/phosphorus additives for oil and many camshaft and engine manufacturers now recommend that an additive be used in initial break-in and for regular use.

All engine oils are rated for viscosity by the SAE as well as additive content by the API; passenger car ratings are two-letter designations that start with “S.” Heavy-duty or off-road equipment ratings start with “C.” The current API oil rating for passenger cars (gasoline engines) is SM and for trucks (diesel engines) CJ-4. Within these designations, you can determine how much zinc and how many other chemicals are present in the ILSAC (multi-viscosity) oils. These levels do not apply to straight-weight oils. If levels in the ILSAC oils are too high for the API specification, they cannot be rated for the current specification unless the container specifies “for racing or off-road use only” or “for use in classic cars.” This has caused oil companies to reduce levels of many additives, including zinc and phosphorus, to the required maximum in order to meet the current specification. Listed here are the current specifications for maximum amounts of additives to achieve the API ratings. P is phosphorus, Zn is zinc, and B is boron. Each figure is total parts per million of additives. These can also be roughly expressed in percentages by multiplying by .0001 (1301 PPM = .13 percent, 994 PPM = .099 percent)

API P Zn B
SJ 1301 1280 151
CI-4 1150 1374 83
SL 994 1182 133
CJ-4 819 1014 26
SM 770 939 127
Most engine and engine component manufacturers recommend zinc and phosphorus content of more than 1,200 PPM for break-in; in fact, many will void warranties on camshafts or crate engines if this minimum is not found in the oil sample you supply when returning broken parts for warranty. For this reason, many manufacturers produce their own zinc additives or oils with supplementary zinc included; GM even offers its own break-in oil with additional ZDDP. With respect to readily available oil, you can see from the chart that, if you can find oil still on the shelf rated SJ or SL, you can use them, but you are right on the cusp of voiding a warranty. New SM oils are just not going to cut it unless they have a zinc additive to boost the rating and one of the zinc supplements should be used with these oils or oils containing additional ZDDP additives are recommended. Some enthusiasts have recommended using commercially rated CI-4 15W40 diesel oil to meet the zinc and phosphorus additive requirement; however, CI-4 is an old specification and hard to locate. You can see that the CJ-4 specification that now supersedes it is well below acceptable levels. Our best recommendation is that you contact your oil supplier for exact additive contents. Many straight-weight oils do not have to meet the ILSAC API specifications to be sold as SM or CJ-4, so this may be an alternative. Classic car oils with elevated levels of ZDDP/ZDTP are also being offered by many suppliers. Regardless, if you are purchasing off-the-shelf oil for your classic car, ILSAC multi-viscosity oils rated SM or CJ-4 should have stated zinc and phosphorus additive supplements for use in older engines or an additional separate additive should be purchased and used with the new oil. As the new API rating SN becomes available in the next year, even more caution should be taken as the levels will be reduced even further.

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Wes K
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cabinfever
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PostPosted: Fri Aug 16, 2013 11:44 am    Post subject: Reply with quote

I have done a little research on this topic and found three manufactures that sell a ZDDP product. Depending on product, the dosage is 2 to 4 oz per oil change. The three products are Eastwood ZDDP Additive, ZDDPlus, and ZDDP Maxx. I decided to go with ZDDPlus and will be using it with modern 10W-30 motor oil.

Others have suggested the use of Valvoline VR1 racing oil. According to Valvoline it has a 1300ppm zinc and 1200ppm phosphorus content. Some have cautioned against the use of racing oils in classic cars because racing oils are made for short term use between changes and therefore may not have contain sufficient levels of other additives.
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